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Which of the following compounds has an atom with an unfilled valence shell of electrons?


A) H2O
B) BCl3
C) CH4
D) CO2

E) C) and D)
F) B) and D)

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What is the formal charge of the carbon in carbon dioxide (CO2) when drawn with two double bonds?


A) +1
B) 0
C) -1
D) -2

E) B) and D)
F) A) and D)

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When forming molecular orbitals from atomic orbitals,what is the order of increasing C-H bond strength for the following set? When forming molecular orbitals from atomic orbitals,what is the order of increasing C-H bond strength for the following set?   A) II < I < III B) III < I < II C) III < II < I D) I < II < III


A) II < I < III
B) III < I < II
C) III < II < I
D) I < II < III

E) B) and D)
F) A) and C)

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Which atomic orbitals overlap to form the C-H s bonding molecular orbitals of ethylene,H2C=CH2?


A) C2p + H1s
B) Csp + H1s
C) Csp3 + H1s
D) Csp2 + H1s

E) A) and B)
F) A) and D)

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Which of the following statements about electronegativity and the periodic table is true?


A) Electronegativity decreases across a row of the periodic table.
B) Electronegativity increases down a column of the periodic table.
C) Electronegativity increases across a row of the periodic table.
D) Electronegativity does not change down a column of the periodic table.

E) B) and C)
F) A) and D)

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Which compound contains the most polar bond? Which compound contains the most polar bond?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and C)
F) None of the above

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Which of the following Lewis structures is correct? Which of the following Lewis structures is correct?   A) I,II B) I,III C) II,III D) III,IV


A) I,II
B) I,III
C) II,III
D) III,IV

E) B) and D)
F) All of the above

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Which of the following is the appropriate conversion of (CH3) 2CHOCH2CH2CH2OH to a skeletal structure? Which of the following is the appropriate conversion of (CH<sub>3</sub>) <sub>2</sub>CHOCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>OH to a skeletal structure?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) None of the above
F) A) and B)

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How many electrons are around phosphorus in phosphoric acid (H3PO4) ?


A) 6
B) 8
C) 10
D) 12

E) All of the above
F) A) and B)

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Which of the following molecules has non-polar covalent bonds?


A) CO2
B) N2
C) CCl4
D) HF

E) A) and B)
F) A) and C)

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Which of the following is the appropriate conversion of the condensed structure,CH3COCH3,to a Lewis structure? Which of the following is the appropriate conversion of the condensed structure,CH<sub>3</sub>COCH<sub>3</sub>,to a Lewis structure?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) C) and D)
F) B) and C)

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Determine the geometry around the indicated atom in each species. Determine the geometry around the indicated atom in each species.   A) I = Linear; II = tetrahedral; III = trigonal planar; IV = tetrahedral B) I = Linear; II = tetrahedral; III = trigonal planar; IV = linear C) I = Trigonal planar; II = linear; III = tetrahedral; IV = trigonal planar D) I = Tetrahedral; II = trigonal planar; III = linear; IV = tetrahedral


A) I = Linear; II = tetrahedral; III = trigonal planar; IV = tetrahedral
B) I = Linear; II = tetrahedral; III = trigonal planar; IV = linear
C) I = Trigonal planar; II = linear; III = tetrahedral; IV = trigonal planar
D) I = Tetrahedral; II = trigonal planar; III = linear; IV = tetrahedral

E) B) and D)
F) All of the above

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Which of the following would you expect to have ionic bonds?


A) CO
B) FBr
C) NF3
D) NaCl

E) B) and C)
F) A) and D)

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How many constitutional isomers are there for a molecule having the molecular formula C2H6O?


A) 1
B) 2
C) 3
D) 4

E) All of the above
F) C) and D)

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Which of the following statements about resonance structures is true?


A) Resonance structures have the same placement of electrons but different arrangement of atoms.
B) Resonance structures have the same placement of atoms but different arrangement of electrons.
C) Resonance structures have the same placement of atoms and the same arrangement of electrons.
D) Resonance structures have different placement of atoms and different arrangement of electrons.

E) B) and C)
F) A) and D)

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What is the hybridization of the nitrogen atom in the ammonium cation,NH4+?


A) sp3
B) sp2
C) sp
D) p

E) A) and B)
F) None of the above

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Rank the following atoms in order of increasing electronegativity,putting the least electronegative first. Rank the following atoms in order of increasing electronegativity,putting the least electronegative first.   A) I < II < III < IV B) I < IV < II < III C) III < II < IV < I D) I < II < IV < III


A) I < II < III < IV
B) I < IV < II < III
C) III < II < IV < I
D) I < II < IV < III

E) All of the above
F) C) and D)

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